They've agreed to join us.

- We got word from our friends. They've agreed to join us. / Мы получили известия от наших друзей. Они согласились к нам присоединиться.

That's them.

- Is that them? / Это они?

- That's them. / Это они.

They were just leaving.

- How long will you guests be staying here? / Сколько здесь еще пробудут твои гости?

- They were just leaving. / Они как раз уходят.

They play ice-hockey. (постоянно)

They're playing ice-hockey. (в данный момент)